Neighbouring double bond participation in exo 5-hydroxybicyclo[2.2.2]oct-2-ene tosylate.

dc.contributor.author	O'Farrell, S.
dc.date.accessioned	2009-04-17T15:57:33Z
dc.date.available	2009-04-17T15:57:33Z
dc.date.created	1962
dc.date.issued	1962
dc.degree.level	Masters
dc.degree.name	M.Sc.
dc.description.abstract	The synthesis of the previously unknown exo-5-hydroxybicyclo[2.2.2]oct-2-ene is described, and its behavior under solvolysis in acetic acid is reported. The end product of the acetolysis is unrearranged and the rate is the fastest yet measured in the bicyclo[2.2.2]octane series. This result supports the theory of homoallylic resonance in the intermediate transition state for the solvolysis reaction. The construction of a preparative-scale vapour-phase chromatograph is described.
dc.format.extent	40 p.
dc.identifier.citation	Source: Masters Abstracts International, Volume: 45-06, page: 3166.
dc.identifier.uri	http://hdl.handle.net/10393/10552
dc.identifier.uri	http://dx.doi.org/10.20381/ruor-8349
dc.publisher	University of Ottawa (Canada)
dc.subject.classification	Chemistry, Organic.
dc.title	Neighbouring double bond participation in exo 5-hydroxybicyclo[2.2.2]oct-2-ene tosylate.
dc.type	Thesis

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