Peng, Hao2013-11-072013-11-0720102010Source: Masters Abstracts International, Volume: 49-06, page: 3858.http://hdl.handle.net/10393/28874http://dx.doi.org/10.20381/ruor-19484Metal-free hydroamination approaches were investigated to afford aromatic nitrogen heterocycles. Several substrates were synthesized to test different sequences such as 6-endo-dig and 6-exo-dig cyclization. The desired reactivity was observed for each of the desired routes, which were discussed in Chapter 2. More research is needed for optimization in the future.* *Please refer to dissertation for diagrams.157 p.enChemistry, Organic.Investigations toward metal-free hydroamination approaches to aromatic nitrogen heterocyclesThesis