Electron transfer and multi-atom abstraction reactions betweenatomic metal anions and NO, NO2and SO2J

Description
Title: Electron transfer and multi-atom abstraction reactions betweenatomic metal anions and NO, NO2and SO2J
Authors: Mayer, Paul M
Butson, Jeffery M
Curtis, Sharon
Date: 2016
Abstract: The atomic metal anions Fe¯, Cs¯, Cu¯ and Ag¯ were reacted with NO, NO2 and SO2 to form intact NO¯, NO2¯ and SO2¯ with no fragmentation. Yields for the molecular anions ranged from 4 to 97% and were found to correlate to the exothermicity of the electron transfer process. Sequential oxygen atom extraction was found to take place between the metal anions and NO and NO2. Reactions between NO2 and Fe¯ resulted in FeO¯, FeO2¯ and FeO3¯ while reactions of Cu¯ with NO2 resulted in CuO¯ and CuO2¯. Reactions of Cu¯ and Ag¯ with NO resulted in CuO¯ and AgO¯ respectively.
URL: http://www.sciencedirect.com/science/article/pii/S0009261416301609
http://hdl.handle.net/10393/34529
DOI: 10.1016/j.cplett.2016.03.044
CollectionChimie // Chemistry
Files
Paper 2_v12.docx538.03 kBMicrosoft Word XMLOpen